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Beilstein J. Org. Chem. 2014, 10, 2215–2221, doi:10.3762/bjoc.10.229
Graphical Abstract
Figure 1: Erythromycin (1), the archetypal macrolide; sophorlipid lactone 2, a glycolipid macrolactone; β-D-g...
Scheme 1: Synthesis of macrolides 5 and 6 by a ring closing metathesis strategy.
Figure 2: Structure of macrolide 3; a) schematic representation of 3 emphasizing four-atom planar units of th...
Figure 3: Structures of 5 and 6 from X-ray crystallographic data; a) and b) side views of 5 (a) and 6 (b) wit...